Localized Surface Plasmon Resonance Imaging: Simultaneous Single Nanoparticle Spectroscopy and Diffusional Dynamics
نویسندگان
چکیده
A wide-field localized surface plasmon resonance (LSPR) imaging method using a liquid crystal tunable filter is used to measure the scattering spectra of multiple Ag nanoparticles in parallel. This method provides the ability to characterize moving Ag nanoparticles by measuring the scattering spectra of the particles while simultaneously tracking their motion. Consequently, single-particle diffusion coefficients can be determined. As an example, several single Ag nanoprisms are tracked, the LSPR scattering spectrum of each moving particle is obtained, and the single-particle diffusion coefficient is determined from its trajectory. Coupling diffusion information with spectral information in real time is a significant advance and addresses many scientific problems, both fundamental and biological, such as cell membrane protein diffusion, functional plasmonic distributions, and nanoparticle growth mechanisms.
منابع مشابه
Hydrogen sensing by localized surface plasmon resonance in colloidal solutions of Au-WO3-Pd
Nowadays, hydrogen has attracted significant attention as a next generation clean energy source. Hydrogen is highly flammable, so detection of hydrogen gas is required. Gold nanoparticle based localized surface plasmon resonance (LSPR) is an advanced and powerful sensing technique, which is well known for its high sensitivity to surrounding refractive index change in the local environment. We p...
متن کاملExploring the Unique Characteristics of LSPR Biosensing
Plasmonic biosensors based on the localized surface plasmon resonance (LSPR) of metal nanoparticles have been developed using both nanoparticle arrays and single nanoparticles. We introduce LSPR biosensing by describing the initial experiments performed using both model systems and disease biomarkers. LSPR shift-enhancement methods, exploitation of the short electromagnetic field decay length, ...
متن کاملStructural and optical characterization of single nanoparticles and single molecule SERS
Although plasmonic nanoparticles are widely utilized in spectroscopy and sensing applications, a quantitative structure-function relationship is lacking. In this proceeding, we discuss measurements of single noble metal nanoparticles using localized surface plasmon resonance (LSPR) spectroscopy, surface-enhanced Raman spectroscopy (SERS), and transmission electron microscopy (TEM) to elucidate ...
متن کاملAdvances in localized surface plasmon resonance spectroscopy biosensing.
In recent years, localized surface plasmon resonance (LSPR) spectroscopy advancements have made it a sensitive, flexible tool for probing biological interactions. Here, we describe the basic principles of this nanoparticle-based sensing technique, the ways nanoparticles can be tailored to optimize sensing, and examples of novel LSPR spectroscopy applications. These include detecting small molec...
متن کاملCalculation of the Induced Charge Distribution on the Surface of a Metallic Nanoparticle Due to an Oscillating Dipole Using Discrete Dipole Approximation method
In this paper, the interaction between an oscillating dipole moment and a Silver nanoparticle has been studied. Our calculations are based on Mie scattering theory and discrete dipole approximation(DDA) method.At first, the resonance frequency due to excitingthe localized surface plasmons has been obtained using Mie scattering theory and then by exciting a dipole moment in theclose proximity of...
متن کامل